The effect of oxygen and nitrogen functional groups on the electrochemical performance of ordered carbon

Ordered carbon (OC) has been synthesised via replication strategy by using Santa Barbara Amorphous (SBA)-15 as a template. The successful replication process has been proven by nitrogen adsorption-desorption analyzer and transmission electron microscopy (TEM). The OC showed well-aligned mesopore sys...

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Bibliographic Details
Main Authors: Hannah Razman, Nur Izzatie, Endud, Salasiah, Misnon, Izan Izwan
Format: Article
Language:English
Published: Penerbit UTM Press 2019
Subjects:
Online Access:http://eprints.utm.my/id/eprint/84754/1/SalasiahEndud2019_TheEffectofOxygenandNitrogenFunctional.pdf
http://eprints.utm.my/id/eprint/84754/
https://dx.doi.org/10.11113/jt.v81.12827
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Institution: Universiti Teknologi Malaysia
Language: English
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Summary:Ordered carbon (OC) has been synthesised via replication strategy by using Santa Barbara Amorphous (SBA)-15 as a template. The successful replication process has been proven by nitrogen adsorption-desorption analyzer and transmission electron microscopy (TEM). The OC showed well-aligned mesopore system, similar to the SBA-15 template. The oxygen and nitrogen functional groups introduced were identified by X-ray photoelectron spectroscopy (XPS). Electrochemical performance of the oxygen containing OC (OC-O), nitrogen containing OC (OC-N), and oxygen nitrogen containing OC (OC-ON) was then evaluated by cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) using a three electrode system in 1M KOH aqueous electrolyte. The OC-O, OC-N, and OC-ON showed significant increment in specific capacitance, CS and exhibited good capacitance retention (CR, %) over high scan rate and current density.