Development and material properties of poly(lactic acid)/poly(3-hydroxybutyrate-co−3-hydroxyvalerate)-based nanocrystalline cellulose nanocomposites

This study is focused on the development and analysis of the thermal and structural behavior of nanocrystalline cellulose (NCC)-based bionanocomposites (BCs). Nanocrystalline cellulose was prepared by controlled acid hydrolysis of oil palm empty fruit bunch fibers. The resulting NCC was surface modi...

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Bibliographic Details
Main Authors: Dasan, Y.K., Bhat, A.H., Faiz, A.
Format: Article
Published: John Wiley and Sons Inc. 2017
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84990235265&doi=10.1002%2fapp.44328&partnerID=40&md5=56430f8f3ff303fa4a8f21479c259aa9
http://eprints.utp.edu.my/19615/
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Institution: Universiti Teknologi Petronas
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Summary:This study is focused on the development and analysis of the thermal and structural behavior of nanocrystalline cellulose (NCC)-based bionanocomposites (BCs). Nanocrystalline cellulose was prepared by controlled acid hydrolysis of oil palm empty fruit bunch fibers. The resulting NCC was surface modified using TEMPO-mediated oxidation and solvent exchange methods for surface functionalization and also to improve dispersion of fillers. Solvent exchange NCC reinforced polymer blend containing poly(lactic acid)/poly-(3-hydroxybutyrate-co-3-hydroxyvalerate) was prepared by using solution casting technique at various NCC loading percentages. The addition of NCC resulted in the improvement of structural, thermal, and mechanical properties of BCs as compared to that of the polymer blend. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44328. © 2016 Wiley Periodicals, Inc.