Study of 1-(2-hydroxyethyle) 3-methylimidazolium halide as thermodynamic inhibitors

• Main Authors: Nashed, O., Sabil, K.M., Lal, B., Ismail, L., Jaafar, A.J.
• Format: Article
• Published: Trans Tech Publications Ltd 2014
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914146120&doi=10.4028%2fwww.scientific.net%2fAMM.625.337&partnerID=40&md5=c675f98b58b5f53a982672734e14f4a5; http://eprints.utp.edu.my/31930/
• Institution: Universiti Teknologi Petronas

In this study, the performance of 1-(2-Hydroxyethyle) 3-methylimidazolium chloride OH-EMIMCl and 1-(2-Hydroxyethyle) 3-methylimidazolium bromide OH-EMIMBr was investigated as thermodynamic gas hydrate inhibitors. The dissociation temperature was determined for methane gas hydrates using a high pressure micro deferential scanning calorimeter at a pressure range of 36-97 bar. Both ionic liquids (ILs) were studied at concentrations of 5, 10, 15, 20 and 25 wt% then their performance was compared with commercially available inhibitors. It was observed that both ILs shift the methane hydrate equilibrium curve to lower temperature and higher pressure; and the performance of OH-EMIMCl is better than OH-EMIMBr. Nevertheless both of them were found to be less effective compared to methanol and mono ethylene glycol. © 2014 Trans Tech Publications, Switzerland.