Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review

Here in, we present a review on the adsorption of dyes and pharmaceuticals from water onto UiO (Universitetet i Oslo) metal�organic frameworks (MOFs). The MOFs possessed distinctive and promising properties, uncommon to other conventional adsorbents, such as ultra-porosity and remarkable stability...

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Main Authors: Zango, Z.U., Jumbri, K., Sambudi, N.S., Abu Bakar, H.H., Garba, Z.N., Isiyaka, H.A., Saad, B.
Format: Article
Published: Elsevier Ltd 2021
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118776285&doi=10.1016%2fj.poly.2021.115515&partnerID=40&md5=0446259ec513412a32264c4acf4ad049
http://eprints.utp.edu.my/32448/
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spelling my.utp.eprints.324482022-03-29T05:26:20Z Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review Zango, Z.U. Jumbri, K. Sambudi, N.S. Abu Bakar, H.H. Garba, Z.N. Isiyaka, H.A. Saad, B. Here in, we present a review on the adsorption of dyes and pharmaceuticals from water onto UiO (Universitetet i Oslo) metal�organic frameworks (MOFs). The MOFs possessed distinctive and promising properties, uncommon to other conventional adsorbents, such as ultra-porosity and remarkable stability, worthy of being super adsorbents for pollutants adsorption from water. They have shown prodigious performance towards the adsorption of both dyes and pharmaceuticals from the aqueous medium at both lower and higher concentrations. The vast adsorption efficiency of the MOFs is heavily attributed to their high Brunauer-Emmett-Teller (BET) surface areas and pore volume, providing abundant adsorption sites for the pollutants. The binding affinity of the MOFs for the dyes and pharmaceuticals adsorption has been elucidated by the different interactions such as electrostatic, hydrogen bonding and �-� stacking, often dictated by the surface charged of the target pollutant and the zeta potential on the MOF's surface. The MOFs have shown higher efficiency even in multi-component systems. The ease for the regeneration of the MOFs using common organic solvents and the impressive performance for repeated cycles has been outstanding. The MOFs were thus regarded as superior over conventional porous adsorbents and commendable for large scale applications. © 2021 Elsevier Ltd Elsevier Ltd 2021 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118776285&doi=10.1016%2fj.poly.2021.115515&partnerID=40&md5=0446259ec513412a32264c4acf4ad049 Zango, Z.U. and Jumbri, K. and Sambudi, N.S. and Abu Bakar, H.H. and Garba, Z.N. and Isiyaka, H.A. and Saad, B. (2021) Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review. Polyhedron, 210 . http://eprints.utp.edu.my/32448/
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country Malaysia
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description Here in, we present a review on the adsorption of dyes and pharmaceuticals from water onto UiO (Universitetet i Oslo) metal�organic frameworks (MOFs). The MOFs possessed distinctive and promising properties, uncommon to other conventional adsorbents, such as ultra-porosity and remarkable stability, worthy of being super adsorbents for pollutants adsorption from water. They have shown prodigious performance towards the adsorption of both dyes and pharmaceuticals from the aqueous medium at both lower and higher concentrations. The vast adsorption efficiency of the MOFs is heavily attributed to their high Brunauer-Emmett-Teller (BET) surface areas and pore volume, providing abundant adsorption sites for the pollutants. The binding affinity of the MOFs for the dyes and pharmaceuticals adsorption has been elucidated by the different interactions such as electrostatic, hydrogen bonding and �-� stacking, often dictated by the surface charged of the target pollutant and the zeta potential on the MOF's surface. The MOFs have shown higher efficiency even in multi-component systems. The ease for the regeneration of the MOFs using common organic solvents and the impressive performance for repeated cycles has been outstanding. The MOFs were thus regarded as superior over conventional porous adsorbents and commendable for large scale applications. © 2021 Elsevier Ltd
format Article
author Zango, Z.U.
Jumbri, K.
Sambudi, N.S.
Abu Bakar, H.H.
Garba, Z.N.
Isiyaka, H.A.
Saad, B.
spellingShingle Zango, Z.U.
Jumbri, K.
Sambudi, N.S.
Abu Bakar, H.H.
Garba, Z.N.
Isiyaka, H.A.
Saad, B.
Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
author_facet Zango, Z.U.
Jumbri, K.
Sambudi, N.S.
Abu Bakar, H.H.
Garba, Z.N.
Isiyaka, H.A.
Saad, B.
author_sort Zango, Z.U.
title Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
title_short Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
title_full Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
title_fullStr Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
title_full_unstemmed Selective adsorption of dyes and pharmaceuticals from water by UiO metal�organic frameworks: A comprehensive review
title_sort selective adsorption of dyes and pharmaceuticals from water by uio metal�organic frameworks: a comprehensive review
publisher Elsevier Ltd
publishDate 2021
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118776285&doi=10.1016%2fj.poly.2021.115515&partnerID=40&md5=0446259ec513412a32264c4acf4ad049
http://eprints.utp.edu.my/32448/
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