A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol.
tr. 220-227
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oai:112.137.131.14:VNU_123-614552018-03-22T20:02:34Z A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. Phung, Nhu Hoa Nguyen, Thi Thu Trang Nguyen, Tien Tuan Anh Pham, Van Phong Nguyen, Van Ky Solanesyl Camphorate antiseptic wound healing challenging coupling solvent-free tr. 220-227 We have developed two esterification strategies fora challenging coupling between camphoric acid and solanesol to achieve a hybrid natural product - solanesyl camphorate. Both synthetic strategies applied the classic activationmode of carboxylic acid group by anhydride formation to overcome the difficulties caused by steric hindrance and the difference in polarity of two reactants. The first method took advantages of easy prepared camphoric anhydride from camphoric acid, whereas the second one allowed direct esterification via in situanhydride formation. Moreover, no solvent is required in synthetic process. This work would provide greener approaches for syntheses of hybrid esters from similar natural products. 2018-03-22T03:55:14Z 2018-03-22T03:55:14Z 2016 Article 2588-1140 http://repository.vnu.edu.vn/handle/VNU_123/61455 other Tập 32;Số 4 application/pdf H. : ĐHQGHN |
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Solanesyl Camphorate antiseptic wound healing challenging coupling solvent-free |
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Solanesyl Camphorate antiseptic wound healing challenging coupling solvent-free Phung, Nhu Hoa Nguyen, Thi Thu Trang Nguyen, Tien Tuan Anh Pham, Van Phong Nguyen, Van Ky A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
description |
tr. 220-227 |
format |
Article |
author |
Phung, Nhu Hoa Nguyen, Thi Thu Trang Nguyen, Tien Tuan Anh Pham, Van Phong Nguyen, Van Ky |
author_facet |
Phung, Nhu Hoa Nguyen, Thi Thu Trang Nguyen, Tien Tuan Anh Pham, Van Phong Nguyen, Van Ky |
author_sort |
Phung, Nhu Hoa |
title |
A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
title_short |
A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
title_full |
A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
title_fullStr |
A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
title_full_unstemmed |
A Challenging Classic Coupling: Esterification of Camphoric Acid - a Steric - Hindered Polar Carboxylic Acid and Solanesol - a Long - Chain Nonpolar Alcohol. |
title_sort |
challenging classic coupling: esterification of camphoric acid - a steric - hindered polar carboxylic acid and solanesol - a long - chain nonpolar alcohol. |
publisher |
H. : ĐHQGHN |
publishDate |
2018 |
url |
http://repository.vnu.edu.vn/handle/VNU_123/61455 |
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1680966141927751680 |