Novel tetrathiafulvalene derivatives and macrocycles with sugar units: Synthesis and characterization

Novel tetrathiafulvalene (TTF) derivatives an macrocycles containing glucose units were synthesized. TTF is an electron rich molecule capable of pi-pi interaction while glucose is polyhydroxylated and has the ability to form hydrogen bonds. The macrocycle synthesis involves the stepwise deprotection...

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Bibliographic Details
Main Author: Alea, Glenn V.
Format: text
Language:English
Published: Animo Repository 1998
Subjects:
Online Access:https://animorepository.dlsu.edu.ph/etd_doctoral/1216
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Institution: De La Salle University
Language: English
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Summary:Novel tetrathiafulvalene (TTF) derivatives an macrocycles containing glucose units were synthesized. TTF is an electron rich molecule capable of pi-pi interaction while glucose is polyhydroxylated and has the ability to form hydrogen bonds. The macrocycle synthesis involves the stepwise deprotection of cyanoethyl protected TTF, reaction with acetylated dihaloglucose, followed by hydrolysis.