Activation of calcium carbide for the synthesis of acetylenic alcohols

The reaction CaC2 with two equivalents of selected ketones (acetophenone, 2-methylcyclohexanone and cyclohexanone) in the presence of base (e.g. NaOH, KOH, MeOK and T-BuOK) in benzene at room temperature produces acetylenic alcohols in 10%-45% yields. The effect of the nature of counter ion of the b...

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Bibliographic Details
Main Author: Tardaguila, Alex A.
Format: text
Language:English
Published: Animo Repository 2003
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Online Access:https://animorepository.dlsu.edu.ph/etd_masteral/3172
https://animorepository.dlsu.edu.ph/context/etd_masteral/article/10010/viewcontent/CDTG003688_P.pdf
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Institution: De La Salle University
Language: English