Approaches to the synthesis of a novel sugar-derivatized tetrathiafulvalene
Several approaches towards the synthesis of a novel sugar-derivatized tetrathiafulvalene (1) are carried out. However, initial attempts to attach three different monosaccharides onto the 1,3-dithiole-2-thione framework (2) as precursors for the TTFs were unsuccessful. Structural factors such as size...
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| Format: | text |
| Language: | English |
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Animo Repository
1998
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| Online Access: | https://animorepository.dlsu.edu.ph/etd_masteral/1900 https://animorepository.dlsu.edu.ph/cgi/viewcontent.cgi?article=8738&context=etd_masteral |
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| Institution: | De La Salle University |
| Language: | English |
| Summary: | Several approaches towards the synthesis of a novel sugar-derivatized tetrathiafulvalene (1) are carried out. However, initial attempts to attach three different monosaccharides onto the 1,3-dithiole-2-thione framework (2) as precursors for the TTFs were unsuccessful. Structural factors such as size and position of linkage seem to be the primary determining factor. [Insert diagrams here.]In addition to these, further experimentation on a previously synthesized sugar-functionalized 1,3-dithiole-2-thione show that coupling using triethylphosphite to form TTFs are incompatible. |
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