Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)

A TTF derivative, 5, (2,3-bis (2-cyanoethylthio)-6,7-ethylenethio TTF) was synthesized, deprotected and reacted with VOSO43H20 following established procedure. The methanol extract of the crude mixture was found to give a greenish-blue needlelike crystal after standing overnight. IR data revealed co...

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Main Author:	Ibasco, Reynaldo R.
Format:	text
Language:	English
Published:	Animo Repository 2002
Subjects:	Chemical reactions Derivatization Heterocyclic compounds Sulphur Medicinal-Pharmaceutical Chemistry
Online Access:	https://animorepository.dlsu.edu.ph/etd_masteral/2668
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Institution:	De La Salle University
Language:	English

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spelling	oai:animorepository.dlsu.edu.ph:etd_masteral-95062021-02-02T00:50:34Z Reaction of tetrathiafulvalene derivative with vanadyl (VO2+) Ibasco, Reynaldo R. A TTF derivative, 5, (2,3-bis (2-cyanoethylthio)-6,7-ethylenethio TTF) was synthesized, deprotected and reacted with VOSO43H20 following established procedure. The methanol extract of the crude mixture was found to give a greenish-blue needlelike crystal after standing overnight. IR data revealed complete deprotection and UV-Vis results showed a coordination of the VO2+ ion with the organic ligand as evidenced by the presence of a band due to a charge transfer between metal and the ligand. The ESI-MS data point to a most likely structure for the complex with a 2:1 ligand to metal ratio. This compound is the first reported TTF-dithiolate complex with VO2+. 2002-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/etd_masteral/2668 Master's Theses English Animo Repository Chemical reactions Derivatization Heterocyclic compounds Sulphur Medicinal-Pharmaceutical Chemistry
institution	De La Salle University
building	De La Salle University Library
continent	Asia
country	Philippines Philippines
content_provider	De La Salle University Library
collection	DLSU Institutional Repository
language	English
topic	Chemical reactions Derivatization Heterocyclic compounds Sulphur Medicinal-Pharmaceutical Chemistry
spellingShingle	Chemical reactions Derivatization Heterocyclic compounds Sulphur Medicinal-Pharmaceutical Chemistry Ibasco, Reynaldo R. Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
description	A TTF derivative, 5, (2,3-bis (2-cyanoethylthio)-6,7-ethylenethio TTF) was synthesized, deprotected and reacted with VOSO43H20 following established procedure. The methanol extract of the crude mixture was found to give a greenish-blue needlelike crystal after standing overnight. IR data revealed complete deprotection and UV-Vis results showed a coordination of the VO2+ ion with the organic ligand as evidenced by the presence of a band due to a charge transfer between metal and the ligand. The ESI-MS data point to a most likely structure for the complex with a 2:1 ligand to metal ratio. This compound is the first reported TTF-dithiolate complex with VO2+.
format	text
author	Ibasco, Reynaldo R.
author_facet	Ibasco, Reynaldo R.
author_sort	Ibasco, Reynaldo R.
title	Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
title_short	Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
title_full	Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
title_fullStr	Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
title_full_unstemmed	Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)
title_sort	reaction of tetrathiafulvalene derivative with vanadyl (vo2+)
publisher	Animo Repository
publishDate	2002
url	https://animorepository.dlsu.edu.ph/etd_masteral/2668
_version_	1712575078255820800

Reaction of tetrathiafulvalene derivative with vanadyl (VO2+)

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