Sulfur-rich CpCo(dithiolene) complexes: Isostructural or non-isostructural couples of CpCo(III) with CpNi(III) dithiolene complexes

• Main Authors: Nomura, Mitsushiro, Kondo, Shigemi, Yamashita, Souichi, Suzuki, Eriko, Toyota, Yoshiko, Alea, Glenn V., Janairo, Gerardo C., Fujita-Takayama, Chikako, Sugiyama, Toru, Kajitani, Masatsugu
• Format: text
• Published: Animo Repository 2010
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/682; https://animorepository.dlsu.edu.ph/context/faculty_research/article/1681/type/native/viewcontent
• Institution: De La Salle University

Eight new sulfur-rich [CpCo(dithiolene)] complexes were synthesized from [Zn(dmit)2]2- as a starting material. The structures, electrochemical behavior and electronic absorption spectra of the sulfur-rich [CpCo(S2C2S2Y)] complexes could be compared with the early data of analogous Ni complexes. [CpC...