Electronic structure mechanism of axial ligands on itinerant electrons and negative magnetoresistance in axially-ligated iron(III) phthalocyanine molecular conductors
Partially-oxidized Iron(III) phthalocyanine (FeIIIPc) with axial CN or Br ligands are molecular conductors with giant negative magnetoresistance. Electron conduction occurs via intermolecular overlapping of Pc π-orbitals, while negative magnetoresistance is brought about by intramolecular interactio...
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Main Authors: | , |
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Format: | text |
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Animo Repository
2018
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Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/2087 https://animorepository.dlsu.edu.ph/context/faculty_research/article/3086/type/native/viewcontent |
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Institution: | De La Salle University |