In situ transesterification of coconut oil using mixtures of methanol and tetrahydrofuran

• Main Authors: Khang, Dinh S., Razon, Luis F., Madrazo, Cynthia F., Tan, Raymond Girard R.
• Format: text
• Published: Animo Repository 2014
• Subjects: Transesterification; Copra; Chemical Engineering
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/2232; https://animorepository.dlsu.edu.ph/context/faculty_research/article/3231/type/native/viewcontent
• Institution: De La Salle University

The conventional biodiesel production method requires oil extraction followed by transesterification with methanol. The solubility of vegetable oils in methanol is low which decreases the overall rate of reaction. To eliminate the oil extraction step and improve the overall reaction rate, simultaneous extraction, esterification and transesterification were conducted by directly mixing methanol and tetrahydrofuran (THF) co-solvent and sulfuric acid catalyst with ground, desiccated coconut meat (copra) in a batch process and continuing the reaction until the system reached steady state. After separation of the mixture, yield was obtained by measuring the content of triglycerides, diglycerides and monoglycerides in the biodiesel phase. The yield increases with THF:methanol ratio, methanol:oil molar ratio and temperature. Within the range of conditions tested, the highest yield achieved was 96.7% at 60. °C, THF:methanol volume ratio of 0.4 and methanol:oil molar ratio of 60:1. The methanol:oil molar ratio is necessarily high in order to completely wet the copra mass, but is still lower than in previous studies by other researchers on in situ transesterification. Product assays show that the resulting biodiesel product is similar to conventionally produced coconut biodiesel. The results indicate that the in situ transesterification of copra using methanol/THF mixtures merits further study. © 2014 The Institution of Chemical Engineers.