Internal mass-transfer limitations on the transesterification of coconut oil using an anionic ion exchange resin in a packed bed reactor

• Main Authors: Co, Charles Edric T., Tan, Millicent C., Diamante, Joseph Angelo R., Yan, Lee Rainier C., Tan, Raymond Girard R., Razon, Luis F.
• Format: text
• Published: Animo Repository 2011
• Subjects: Biodiesel fuels; Transesterification; Coconut oil as fuel; Ion exchange resins; Chemical Engineering
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/2252; https://animorepository.dlsu.edu.ph/context/faculty_research/article/3251/type/native/viewcontent
• Institution: De La Salle University

In this study, a strongly basic anion-exchange resin was used for the transesterification of coconut oil and methanol using a continuous-flow packed-bed reactor. Statistical analysis shows that the observed conversion and apparent bulk reaction rate are insensitive to temperature. This suggests that mass transfer is the rate-determining step. Analysis of the Wagner-Weisz-Wheeler (WWW) modulus shows that the observed reaction rate is strongly influenced by internal mass-transfer resistances (WWW > 4) under most of the experimental conditions used. However, in some tests, the overall reaction rate can be said to be in the transition regime between reaction control and internal mass-transfer control (0.15 < WWW < 4). Extended continuous flow experiments showed no noticeable decline in the catalyst activity even after almost 400 reactor bed void volumes of biodiesel had been produced. These results suggest that the catalyst and thus the overall reactor performance may be further improved by increasing the porosity. © 2011 Elsevier B.V. All rights reserved.