Crystal structure of ruthenium phthalocyanine with diaxial monoatomic ligand: Bis(triphenylphosphine)iminium dichloro(phthalocyaninato(2-)) ruthenium(III)

• Main Authors: Yu, Derrick Ethelbhert, Kikuchi, Akira, Taketsugu, Tetsuya, Inabe, Tamotsu
• Format: text
• Published: Animo Repository 2013
• Subjects: Phthalocyanines; Magnetoresistance; Chemistry
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/3755; https://animorepository.dlsu.edu.ph/context/faculty_research/article/4757/type/native/viewcontent/486318.html
• Institution: De La Salle University

Axially-ligated iron phthalocyanines have been found to be good molecular conductors with giant negative magnetoresistance (GNMR) which originates from a strong intramolecular π-d interaction between the metal and phthalocyanine. Ab initio theoretical calculations showed that substitution of rutheni...