Alkoxyamine-mediated "living" radical polymerization: MS investigation of the early stages of styrene polymerization initiated by cumyl-TEISO

• Main Authors: Cresidio, Salvacion P., Aldabbagh, Fawaz, Busfield, W. Ken, Jenkins, Ian D., Thang, San H., Holdsworth, Clovia Zayas-, Zetterlund, Per B.
• Format: text
• Published: Animo Repository 2001
• Subjects: Polymerization; Free radicals (Chemistry); Nitroxides; Styrene; Chemistry
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/4215
• Institution: De La Salle University

A new series of 1,1,3,3-tetraethylisoindoline-2-oxyl (TEISO)-based alkoxyamines was prepared. The half-lives for thermal dissociation indicated that the most sterically congested cumyl-TEISO alkoxymine had the greatest potential as an initiator for the polymerization of monomers at lower temperature...