Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-...
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oai:animorepository.dlsu.edu.ph:faculty_research-60662022-04-05T08:24:15Z Molecularly imprinted polymers for regioselective amidification of polyfunction precursors Francia, Chris Allen Earl T. Camacho, Drexel H. MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-group in the synthesis of new aspartame compound using SOCI2 from Asp, Phe amino acids & CH3OH precursors. Spectroscopic data (IR, MS, NMR) and N2 adsorption/desorption studies of the MIP and complexes implied mesoporic (19.3Å) polymers that yields low dipeptide products. 2017-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/5390 Faculty Research Work Animo Repository Polymers Aspartame Chemistry |
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Polymers Aspartame Chemistry Francia, Chris Allen Earl T. Camacho, Drexel H. Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
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MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-group in the synthesis of new aspartame compound using SOCI2 from Asp, Phe amino acids & CH3OH precursors. Spectroscopic data (IR, MS, NMR) and N2 adsorption/desorption studies of the MIP and complexes implied mesoporic (19.3Å) polymers that yields low dipeptide products. |
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Francia, Chris Allen Earl T. Camacho, Drexel H. |
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Francia, Chris Allen Earl T. Camacho, Drexel H. |
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Francia, Chris Allen Earl T. |
title |
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
title_short |
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
title_full |
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
title_fullStr |
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
title_full_unstemmed |
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
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molecularly imprinted polymers for regioselective amidification of polyfunction precursors |
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Animo Repository |
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2017 |
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https://animorepository.dlsu.edu.ph/faculty_research/5390 |
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