Molecularly imprinted polymers for regioselective amidification of polyfunction precursors

Molecularly imprinted polymers for regioselective amidification of polyfunction precursors

MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-...

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Main Authors: Francia, Chris Allen Earl T., Camacho, Drexel H.
Format: text
Published: Animo Repository 2017
Subjects:
Polymers
Aspartame
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/5390
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Institution: De La Salle University
id oai:animorepository.dlsu.edu.ph:faculty_research-6066
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spelling oai:animorepository.dlsu.edu.ph:faculty_research-60662022-04-05T08:24:15Z Molecularly imprinted polymers for regioselective amidification of polyfunction precursors Francia, Chris Allen Earl T. Camacho, Drexel H. MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-group in the synthesis of new aspartame compound using SOCI2 from Asp, Phe amino acids & CH3OH precursors. Spectroscopic data (IR, MS, NMR) and N2 adsorption/desorption studies of the MIP and complexes implied mesoporic (19.3Å) polymers that yields low dipeptide products. 2017-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/5390 Faculty Research Work Animo Repository Polymers Aspartame Chemistry
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
topic Polymers
Aspartame
Chemistry
spellingShingle Polymers
Aspartame
Chemistry
Francia, Chris Allen Earl T.
Camacho, Drexel H.
Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
description MIP bulk was thermopolymerized from l-α-aspartame, 2-methoxy-4-vinylphenol and divinylbenzene; set with 1:6 template-monomer ratio. Semi-empirical computational modelling was used to study stabilization energy of H-bonding between the template & monomer. Free-MIP (ground) was used as protecting-group in the synthesis of new aspartame compound using SOCI2 from Asp, Phe amino acids & CH3OH precursors. Spectroscopic data (IR, MS, NMR) and N2 adsorption/desorption studies of the MIP and complexes implied mesoporic (19.3Å) polymers that yields low dipeptide products.
format text
author Francia, Chris Allen Earl T.
Camacho, Drexel H.
author_facet Francia, Chris Allen Earl T.
Camacho, Drexel H.
author_sort Francia, Chris Allen Earl T.
title Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
title_short Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
title_full Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
title_fullStr Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
title_full_unstemmed Molecularly imprinted polymers for regioselective amidification of polyfunction precursors
title_sort molecularly imprinted polymers for regioselective amidification of polyfunction precursors
publisher Animo Repository
publishDate 2017
url https://animorepository.dlsu.edu.ph/faculty_research/5390
_version_ 1767196273138466816

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