Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain elec...
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| Main Authors: | , , , , |
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| 格式: | text |
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Animo Repository
2010
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| 在線閱讀: | https://animorepository.dlsu.edu.ph/faculty_research/7323 |
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| 機構: | De La Salle University |
| 總結: | Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex. |
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