Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain elec...
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2010
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oai:animorepository.dlsu.edu.ph:faculty_research-78302022-10-12T23:27:22Z Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering Yu, Derrick Ethelbhert C. Gacho, Eduardo H. Janairo, Gerardo C. Ang, P. T. Tan, S.M.D. Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex. 2010-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/7323 Faculty Research Work Animo Repository Electric conductors Heterocyclic compounds Chemical Engineering |
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Electric conductors Heterocyclic compounds Chemical Engineering |
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Electric conductors Heterocyclic compounds Chemical Engineering Yu, Derrick Ethelbhert C. Gacho, Eduardo H. Janairo, Gerardo C. Ang, P. T. Tan, S.M.D. Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| description |
Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex. |
| format |
text |
| author |
Yu, Derrick Ethelbhert C. Gacho, Eduardo H. Janairo, Gerardo C. Ang, P. T. Tan, S.M.D. |
| author_facet |
Yu, Derrick Ethelbhert C. Gacho, Eduardo H. Janairo, Gerardo C. Ang, P. T. Tan, S.M.D. |
| author_sort |
Yu, Derrick Ethelbhert C. |
| title |
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| title_short |
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| title_full |
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| title_fullStr |
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| title_full_unstemmed |
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering |
| title_sort |
skewered cyano-bridged cobalt naphthalocyanine polymer: an electron transport engineering |
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Animo Repository |
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2010 |
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https://animorepository.dlsu.edu.ph/faculty_research/7323 |
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