Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering

Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain elec...

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المؤلفون الرئيسيون: Yu, Derrick Ethelbhert C., Gacho, Eduardo H., Janairo, Gerardo C., Ang, P. T., Tan, S.M.D.
التنسيق: text
منشور في: Animo Repository 2010
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الوصول للمادة أونلاين:https://animorepository.dlsu.edu.ph/faculty_research/7323
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spelling oai:animorepository.dlsu.edu.ph:faculty_research-78302022-10-12T23:27:22Z Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering Yu, Derrick Ethelbhert C. Gacho, Eduardo H. Janairo, Gerardo C. Ang, P. T. Tan, S.M.D. Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex. 2010-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/7323 Faculty Research Work Animo Repository Electric conductors Heterocyclic compounds Chemical Engineering
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
topic Electric conductors
Heterocyclic compounds
Chemical Engineering
spellingShingle Electric conductors
Heterocyclic compounds
Chemical Engineering
Yu, Derrick Ethelbhert C.
Gacho, Eduardo H.
Janairo, Gerardo C.
Ang, P. T.
Tan, S.M.D.
Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
description Naphthalocyanines (Nc) are ideal molecular conductors due to their flat and fully-conjugated structures. Attachment of a central metal (Co) and dicyano (CN) axial ligands to Nc produced CN-bridged cobalt naphthalocynanine, a skewed-type polymer complex. The polymeric species enabled intra-chain electron transport through the CN bridge by which, coupled with the inter-chain π-π overlaps, produced a multi-dimensional electronic system. This molecular design has decreased the electrical resistivity by 5 orders relative to the monomeric Co(Nc) with di-axial CN complex.
format text
author Yu, Derrick Ethelbhert C.
Gacho, Eduardo H.
Janairo, Gerardo C.
Ang, P. T.
Tan, S.M.D.
author_facet Yu, Derrick Ethelbhert C.
Gacho, Eduardo H.
Janairo, Gerardo C.
Ang, P. T.
Tan, S.M.D.
author_sort Yu, Derrick Ethelbhert C.
title Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
title_short Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
title_full Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
title_fullStr Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
title_full_unstemmed Skewered cyano-bridged cobalt naphthalocyanine polymer: An electron transport engineering
title_sort skewered cyano-bridged cobalt naphthalocyanine polymer: an electron transport engineering
publisher Animo Repository
publishDate 2010
url https://animorepository.dlsu.edu.ph/faculty_research/7323
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