Evaluation of Mott's parameters for hopping conduction in polypyrrole (p-TS)

Conducting polypyyrole (p-TS) films were prepared by anodic deposition of 0.1 M pyrrole and 0.05 M to 0.20 M para-tulouene sulphonate in an aqueous solution. Resistivity versus Temperature measurements of the electrochemically prepared polypyrroles were obtained by Van der Pauw Technique at a temper...

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Main Authors: Rempillo, Ofelia T., Quiroga, Reuben V., Manzano, Maria Carla F., Manzano, Enrique M.
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Published: Animo Repository 2005
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Online Access:https://animorepository.dlsu.edu.ph/faculty_research/8496
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Institution: De La Salle University
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Summary:Conducting polypyyrole (p-TS) films were prepared by anodic deposition of 0.1 M pyrrole and 0.05 M to 0.20 M para-tulouene sulphonate in an aqueous solution. Resistivity versus Temperature measurements of the electrochemically prepared polypyrroles were obtained by Van der Pauw Technique at a temperature range of 88 K ti 298 K. Measurements showed resistivity decreases with temperature. A T -1/4 dependence of the logarithm of resistivity was obtained consistent with Mott's variable range hopping conduction model.