Cationic and Neutral Rotaxanes Having Different Functional Groups in the Axle Molecule and Their Coordination to PtII

• Main Authors: Yu, Gilbert U, Suzaki, Yuji, Osakada, Kohtaro
• Format: text
• Published: Archīum Ateneo 2016
• Subjects: Chemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/10; https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201601554
• Institution: Ateneo De Manila University

Dibenzo[24]crown‐8 (DB24C8) forms rotaxanes with a linear molecule having a dialkylammonium group and a triazole group as well as with the acetylation product of a cationic axle molecule. The former cationic rotaxane is stabilized by multiple intermolecular hydrogen bonds between the NH2+ and oxyeth...