Chirality and asymmetric transformations of axially chiral 4,5-disubstituted phenanthreneamides
We have investigated the rotation barriers of 4-carbamoylphenanthrene and 4-thiocarbamoylphenanthrene and the asymmetric transformations of the novel 4-carboxy-5-carbamoylphenanthrenes. The similar ArC and CN barriers of 92 kJ/mol of 4-carbamoylphenanthrene indicate a strongly correlated process o...
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Main Authors: | , , , |
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Format: | text |
Published: |
Archīum Ateneo
2000
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Online Access: | https://archium.ateneo.edu/chemistry-faculty-pubs/73 https://www.sciencedirect.com/science/article/abs/pii/S0957416600002986 |
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Institution: | Ateneo De Manila University |