Emergent ferromagnetism in ZnO/Al2O3 core-shell nanowires : towards oxide spinterfaces
We report that room-temperature ferromagnetism emerges at the interface formed between ZnO nanowire core and Al2O3 shell although both constituents show mainly diamagnetism. The interface-based ferromagnetism can be further enhanced by annealing the ZnO/Al2O3 core-shell nanowires and activating the...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/100094 http://hdl.handle.net/10220/18441 |
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| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | We report that room-temperature ferromagnetism emerges at the interface formed between ZnO nanowire core and Al2O3 shell although both constituents show mainly diamagnetism. The interface-based ferromagnetism can be further enhanced by annealing the ZnO/Al2O3 core-shell nanowires and activating the formation of ZnAl2O4 phase as a result of interfacial solid-state reaction. High-temperature measurements indicate that the magnetic order is thermally stable up to 750 K. Transmission electron microscopy studies reveal the annealing-induced jagged interfaces, and the extensive structural defects appear to be relevant to the emergent magnetism. Our study suggests that tailoring the spinterfaces in nanostructure-harnessed wide-band-gap oxides is an effective route towards engineered nanoscale architecture with enhanced magnetic properties. |
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