Non-aqueous energy storage devices using graphene nanosheets synthesized by green route

In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and pow...

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Bibliographic Details
Main Authors: Mhamane, Dattakumar, Suryawanshi, Anil, Banerjee, Abhik, Aravindan, Vanchiappan, Ogale, Satishchandra, Srinivasan, Madhavi
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/100325
http://hdl.handle.net/10220/10954
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Institution: Nanyang Technological University
Language: English
Description
Summary:In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and power densities of 60.4 Wh kg–1 and 0.15 kW kg–1, respectively. More importantly, symmetric supercapacitor shows an extraordinary cycleability (5000 cycles) with over 80% of capacitance retention. In addition, Li-storage properties of TRGO are also evaluated in half-cell configuration (Li/TRGO) and shown to deliver a reversible capacity of ∼705 mAh g–1 with good cycleability at constant current density of 37 mA g–1. This result clearly suggests that green-synthesized graphene can be effectively used as a prospective electrode material for non-aqueous energy storage systems such as Li-ion batteries and supercapacitors.