Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins

Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins

In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by pal...

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Main Authors: Wu, Xiaojin, Lu, Yunpeng, Hirao, Hajime, Zhou, Jianrong Steve
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Subjects:
DRNTU::Science::Chemistry
Online Access:https://hdl.handle.net/10356/100544
http://hdl.handle.net/10220/17996
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1005442020-03-07T12:37:16Z Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins Wu, Xiaojin Lu, Yunpeng Hirao, Hajime Zhou, Jianrong Steve School of Physical and Mathematical Sciences DRNTU::Science::Chemistry In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium–hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions. 2013-12-02T09:01:46Z 2019-12-06T20:24:15Z 2013-12-02T09:01:46Z 2019-12-06T20:24:15Z 2013 2013 Journal Article Wu, X., Lu, Y., Hirao, H., & Zhou, J. S. (2013). Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins. Chemistry - A European journal, 19(19), 6014-6020. 0947-6539 https://hdl.handle.net/10356/100544 http://hdl.handle.net/10220/17996 10.1002/chem.201204427 en Chemistry - a European journal
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry
spellingShingle DRNTU::Science::Chemistry
Wu, Xiaojin
Lu, Yunpeng
Hirao, Hajime
Zhou, Jianrong Steve
Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
description In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium–hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wu, Xiaojin
Lu, Yunpeng
Hirao, Hajime
Zhou, Jianrong Steve
format Article
author Wu, Xiaojin
Lu, Yunpeng
Hirao, Hajime
Zhou, Jianrong Steve
author_sort Wu, Xiaojin
title Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
title_short Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
title_full Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
title_fullStr Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
title_full_unstemmed Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins
title_sort achieving vinylic selectivity in mizoroki-heck reaction of cyclic olefins
publishDate 2013
url https://hdl.handle.net/10356/100544
http://hdl.handle.net/10220/17996
_version_ 1681040301881294848

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