Approaching a stable, green twisted heteroacene through “clean reaction” strategy

Approaching a stable, green twisted heteroacene through “clean reaction” strategy

A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreem...

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Bibliographic Details
Main Authors: Wudl, Fred, Zhang, Qichun, Li, Gang, Zhang, Zhonghan, Xiao, Jinchong, Liu, Lei, Zhao, Yanli, Zhang, Hua, Huo, Fengwei, Li, Shuzhou, Ma, Jan, Duong, Hieu M.
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/100883
http://hdl.handle.net/10220/11062
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Institution: Nanyang Technological University
Language: English
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Summary:A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.

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