Reactivity of a distannylene toward potassium graphite : synthesis of a stannylidenide anion

The synthesis and characterization of the stannylidenide anion [LSn:]− (L = 2,6-(CH═NBut)2C6H3) supported by the 2,6-diiminophenyl ligand is described. The reaction of the chlorostannylene [LSnCl] (2) with excess KC8 in diethyl ether at room temperature afforded the distannylene [LSn:]2 (3). The tre...

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Bibliographic Details
Main Authors: Chia, Siew-Peng, Ganguly, Rakesh, Li, Yongxin, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/101124
http://hdl.handle.net/10220/13699
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Institution: Nanyang Technological University
Language: English