Synthesis, characterization, and sensing behavior of an N-heteropentacene

An N-heteropentacene, 1,2,5,6-tetra(5-hexylthiophene-2-yl)-hexaazapentacene (4HP), was synthesized through one-step cyclocondensation reaction. The binding behavior of 4HP toward various cations (Ca2+, Cd2+, Co2+, Cr2+, Cu2+ Fe3+, Hg2+, K+, Li+, Mg2+, Mn2+, Na+, Ni2+, Zn2+, and Pb2) was investigated...

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Main Authors: Li, Gang, Gao, Junkuo, Zhang, Qichun
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2014
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Online Access:https://hdl.handle.net/10356/101206
http://hdl.handle.net/10220/19706
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1012062020-06-01T10:26:38Z Synthesis, characterization, and sensing behavior of an N-heteropentacene Li, Gang Gao, Junkuo Zhang, Qichun School of Materials Science & Engineering DRNTU::Engineering::Materials::Testing of materials An N-heteropentacene, 1,2,5,6-tetra(5-hexylthiophene-2-yl)-hexaazapentacene (4HP), was synthesized through one-step cyclocondensation reaction. The binding behavior of 4HP toward various cations (Ca2+, Cd2+, Co2+, Cr2+, Cu2+ Fe3+, Hg2+, K+, Li+, Mg2+, Mn2+, Na+, Ni2+, Zn2+, and Pb2) was investigated by UV/vis and fluorescence spectroscopy. 4HP demonstrated a selective and sensitive response towards Cu2+ ion, and the detection limit reached 1.2 μM in N,N-dimethylformamide solution. 2014-06-12T07:28:37Z 2019-12-06T20:35:11Z 2014-06-12T07:28:37Z 2019-12-06T20:35:11Z 2014 2014 Journal Article Li, G., Gao, J., & Zhang, Q. (2014). Synthesis, Characterization, and Sensing Behavior of an N-heteropentacene. Asian Journal of Organic Chemistry, 3(2), 203-208. 2193-5807 https://hdl.handle.net/10356/101206 http://hdl.handle.net/10220/19706 10.1002/ajoc.201300210 en Asian journal of organic chemistry © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Engineering::Materials::Testing of materials
spellingShingle DRNTU::Engineering::Materials::Testing of materials
Li, Gang
Gao, Junkuo
Zhang, Qichun
Synthesis, characterization, and sensing behavior of an N-heteropentacene
description An N-heteropentacene, 1,2,5,6-tetra(5-hexylthiophene-2-yl)-hexaazapentacene (4HP), was synthesized through one-step cyclocondensation reaction. The binding behavior of 4HP toward various cations (Ca2+, Cd2+, Co2+, Cr2+, Cu2+ Fe3+, Hg2+, K+, Li+, Mg2+, Mn2+, Na+, Ni2+, Zn2+, and Pb2) was investigated by UV/vis and fluorescence spectroscopy. 4HP demonstrated a selective and sensitive response towards Cu2+ ion, and the detection limit reached 1.2 μM in N,N-dimethylformamide solution.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Li, Gang
Gao, Junkuo
Zhang, Qichun
format Article
author Li, Gang
Gao, Junkuo
Zhang, Qichun
author_sort Li, Gang
title Synthesis, characterization, and sensing behavior of an N-heteropentacene
title_short Synthesis, characterization, and sensing behavior of an N-heteropentacene
title_full Synthesis, characterization, and sensing behavior of an N-heteropentacene
title_fullStr Synthesis, characterization, and sensing behavior of an N-heteropentacene
title_full_unstemmed Synthesis, characterization, and sensing behavior of an N-heteropentacene
title_sort synthesis, characterization, and sensing behavior of an n-heteropentacene
publishDate 2014
url https://hdl.handle.net/10356/101206
http://hdl.handle.net/10220/19706
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