Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium

Reaction of the dimeric species [Cp*IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in C–C bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.

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Main Authors:	Wong, Kai Ning, Mak, Garvin Kar Hang, Fan, Wai Yip, Sridevi, Venugopal Shanmugham, Leong, Weng Kee
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	Chemistry and Biological Chemistry
Online Access:	https://hdl.handle.net/10356/101322 http://hdl.handle.net/10220/18613
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-101322
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spelling	sg-ntu-dr.10356-1013222023-02-28T19:38:47Z Iridafurans from the reaction of [CpIrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium Wong, Kai Ning Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee School of Physical and Mathematical Sciences Chemistry and Biological Chemistry Reaction of the dimeric species [CpIrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in C–C bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally. MOE (Min. of Education, S’pore) Accepted version 2014-01-20T02:19:54Z 2019-12-06T20:36:42Z 2014-01-20T02:19:54Z 2019-12-06T20:36:42Z 2013 2013 Journal Article Wong, K. N., Mak, K. H. G., Fan, W. Y., Sridevi, V. S., & Leong, W. K. (2013). Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes: Dependence of product on polarity of reaction medium. Journal of Organometallic Chemistry, 741-742, 40-46. 0022-328X https://hdl.handle.net/10356/101322 http://hdl.handle.net/10220/18613 10.1016/j.jorganchem.2013.05.021 en Journal of organometallic chemistry © 2013 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2013.05.021]. 7p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	Chemistry and Biological Chemistry
spellingShingle	Chemistry and Biological Chemistry Wong, Kai Ning Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
description	Reaction of the dimeric species [Cp*IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in C–C bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Wong, Kai Ning Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee
format	Article
author	Wong, Kai Ning Mak, Garvin Kar Hang Fan, Wai Yip Sridevi, Venugopal Shanmugham Leong, Weng Kee
author_sort	Wong, Kai Ning
title	Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
title_short	Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
title_full	Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
title_fullStr	Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
title_full_unstemmed	Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
title_sort	iridafurans from the reaction of [cp*ircl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
publishDate	2014
url	https://hdl.handle.net/10356/101322 http://hdl.handle.net/10220/18613
_version_	1759857462162227200

Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium

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