Mixed-sandwich Cp*Cr complexes containing poly(methimazolyl)borates (Cp* = C5Me5) : syntheses and structural and electrochemical studies
Reaction of the scorpionate salts K[HB(mt)3], Na[H2B(mt)2], and Li[HB(mt)2(pz)] with [Cp*CrBr2]2 (1) gave the 15-electron Cr(III) complexes [Cp*Cr{κ3-S,S′,S″-HB(mt)3}]Br (2), [Cp*Cr{κ2-S,S′-H2B(mt)2}Br] (3), and [Cp*Cr{κ2-S,S′-HB(mt)2(pz)}Br] (4) in moderate to high yields. These are the first examp...
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101535 http://hdl.handle.net/10220/13703 |
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| Institution: | Nanyang Technological University |
| Language: | English |