Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines

The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computat...

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Main Authors:	Kumaran, Elumalai, How, Kai Tong Sonia, Ganguly, Rakesh, Li, Yongxin, Leong, Weng Kee
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:	https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-1016252023-02-28T19:42:20Z Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [CpIrCl2]2 afforded the cationic aminocarbene derivatives CpIr(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies. MOE (Min. of Education, S’pore) Accepted version 2014-01-21T08:19:58Z 2019-12-06T20:41:41Z 2014-01-21T08:19:58Z 2019-12-06T20:41:41Z 2013 2013 Journal Article Kumaran, E., How, K. T. S., Ganguly, R., Li, Y., & Leong, W. K. (2013). Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines. Organometallics, 32(15), 4149-4152. https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657 10.1021/om400326c en Organometallics © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om400326c]. 4p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
description	The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [CpIrCl2]2 afforded the cationic aminocarbene derivatives CpIr(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee
format	Article
author	Kumaran, Elumalai How, Kai Tong Sonia Ganguly, Rakesh Li, Yongxin Leong, Weng Kee
author_sort	Kumaran, Elumalai
title	Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
title_short	Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
title_full	Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
title_fullStr	Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
title_full_unstemmed	Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
title_sort	synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
publishDate	2014
url	https://hdl.handle.net/10356/101625 http://hdl.handle.net/10220/18657
_version_	1759856751490891776

Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines

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