Role of local assembly in the hierarchical crystallization of associating colloidal hard hemispheres

• Main Authors: Lei, Qun-li, Hadinoto, Kunn, Ni, Ran
• Other Authors: School of Chemical and Biomedical Engineering
• Format: Article
• Language: English
• Published: 2019
• Subjects: Crystallization; Excluded Volume Interaction; DRNTU::Engineering::Chemical engineering
• Online Access: https://hdl.handle.net/10356/102281; http://hdl.handle.net/10220/48591
• Institution: Nanyang Technological University

Hierarchical self-assembly consisting of local associations of simple building blocks for the formation of complex structures widely exists in nature, while the essential role of local assembly remains unknown. In this work, by using computer simulations, we study a simple model system consisting of associating colloidal hemispheres crystallizing into face-centered-cubic crystals comprised of spherical dimers of hemispheres, focusing on the effect of dimer formation on the hierarchical crystallization. We found that besides assisting the crystal nucleation because of increasing the symmetry of building blocks, the association between hemispheres can also induce both reentrant melting and reentrant crystallization depending on the range of interaction. Especially when the interaction is highly sticky, we observe a novel reentrant crystallization of identical crystals, which melt only in a certain temperature range. This offers another axis in fabricating responsive crystalline materials by tuning the fluctuation of local association.