Heteroleptic Germanium(II) and Tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene

• المؤلفون الرئيسيون: Chia, Siew-Peng, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Physics
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/102860; http://hdl.handle.net/10220/19060

The syntheses and structures of heteroleptic germanium(II) and tin(II) chlorides supported by anionic ligands derived from 2,3-dimethyl-1,4-diaza-1,3-butadiene are described. The reaction of ArN=C(Me)C(Me)=NAr (L, Ar = 2,6-iPr2C6H3) with MeLi in Et2O, followed by treatment with GeCl2·dioxane or SnCl...