Tertiary amine mediated aerobic oxidation of sulfides into sulfoxides by visible-light photoredox catalysis on TiO2
The selective oxidation of sulfides into sulfoxides receives much attention due to industrial and biological applications. However, the realization of this reaction with molecular oxygen at room temperature, which is of importance towards green and sustainable chemistry, remains challenging. Herei...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/102888 http://hdl.handle.net/10220/38492 |
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| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | The selective oxidation of sulfides into sulfoxides receives much attention due to industrial and biological
applications. However, the realization of this reaction with molecular oxygen at room temperature,
which is of importance towards green and sustainable chemistry, remains challenging. Herein, we
develop a strategy to achieve the aerobic oxidation of sulfides into sulfoxides by exploring the synergy
between a tertiary amine and titanium dioxide via visible-light photoredox catalysis. Specifically, titanium
dioxide can interact with triethylamine (TEA) to form a visible-light harvesting surface complex, preluding
the ensuing selective redox reaction. Moreover, TEA, whose stability was demonstrated by a turnover
number of 32, plays a critical role as a redox mediator by shuttling electrons during the oxidation of
sulfide. This work suggests that the addition of a redox mediator is highly functional in establishing
visible-light-induced reactions via heterogeneous photoredox catalysis. |
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