A concerted transfer hydrogenolysis : 1,3,2-diazaphospholene-catalyzed hydrogenation of N=N bond with ammonia-borane

• المؤلفون الرئيسيون: Chong, Che Chang, Hirao, Hajime, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/102918; http://hdl.handle.net/10220/19141
• المؤسسة: Nanyang Technological University

1,3,2-diazaphospholenes catalyze metal-free transfer hydrogenation of a N=N double bond using ammonia–borane under mild reaction conditions, thus allowing access to various hydrazine derivatives. Kinetic and computational studies revealed that the rate-determining step involves simultaneous breakage...