CH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexes

• Main Authors: Xu, Xiangya, Pooi, Benjamin, Hirao, Hajime, Hong, Soon Hyeok
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2014
• 主題: DRNTU::Science::Chemistry
• 在線閱讀: https://hdl.handle.net/10356/102922; http://hdl.handle.net/10220/19149

The role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazo...