CH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexes

• المؤلفون الرئيسيون: Xu, Xiangya, Pooi, Benjamin, Hirao, Hajime, Hong, Soon Hyeok
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/102922; http://hdl.handle.net/10220/19149
• المؤسسة: Nanyang Technological University

The role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazo...