Selective fluorination of alkyl C–H bonds via photocatalysis

Selective fluorination of alkyl C–H bonds via photocatalysis

We report the generation of cationic N-radicals from Selectfluor® via energy transfer with anthraquinone as a photocatalyst for the fluorination of unactivated C–H bonds.

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Bibliographic Details
Main Authors: Kee, Choon Wee, Chin, Kek Foo, Wong, Ming Wah, Tan, Choon-Hong
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry
Online Access:https://hdl.handle.net/10356/103224
http://hdl.handle.net/10220/24396
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Institution: Nanyang Technological University
Language: English
Description
Summary:We report the generation of cationic N-radicals from Selectfluor® via energy transfer with anthraquinone as a photocatalyst for the fluorination of unactivated C–H bonds.

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