[Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles

[Cp∗IrCl2]2 catalyses the cyclization of 2-alkynylanilines into indoles. A wide variety of substrates is tolerated. A reaction pathway involving intramolecular hydroamination is proposed.

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Main Authors: Kumaran, Elumalai, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/103623
http://hdl.handle.net/10220/24547
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1036232023-02-28T19:44:41Z [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles Kumaran, Elumalai Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds [Cp∗IrCl2]2 catalyses the cyclization of 2-alkynylanilines into indoles. A wide variety of substrates is tolerated. A reaction pathway involving intramolecular hydroamination is proposed. MOE (Min. of Education, S’pore) Accepted version 2014-12-26T06:31:12Z 2019-12-06T21:16:32Z 2014-12-26T06:31:12Z 2019-12-06T21:16:32Z 2014 2014 Journal Article Kumaran, E., & Leong, W. K. (2014). [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles. Tetrahedron letters, 55(40), 5495-5498. 0040-4039 https://hdl.handle.net/10356/103623 http://hdl.handle.net/10220/24547 10.1016/j.tetlet.2014.08.053 en Tetrahedron letters © 2014 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Tetrahedron Letters, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.tetlet.2014.08.053]. 10 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Kumaran, Elumalai
Leong, Weng Kee
[Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
description [Cp∗IrCl2]2 catalyses the cyclization of 2-alkynylanilines into indoles. A wide variety of substrates is tolerated. A reaction pathway involving intramolecular hydroamination is proposed.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Kumaran, Elumalai
Leong, Weng Kee
format Article
author Kumaran, Elumalai
Leong, Weng Kee
author_sort Kumaran, Elumalai
title [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
title_short [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
title_full [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
title_fullStr [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
title_full_unstemmed [Cp∗IrCl2]2-catalysed cyclization of 2-alkynylanilines into indoles
title_sort [cp∗ircl2]2-catalysed cyclization of 2-alkynylanilines into indoles
publishDate 2014
url https://hdl.handle.net/10356/103623
http://hdl.handle.net/10220/24547
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