Transitional metal/chalcogen dependant interactions of hairpin DNA with transition metal dichalcogenides, MX2

Owing to the attractive properties that transition metal dichalcogenides (TMDs) display, they have found recent application in the fabrication of biosensing devices. These devices involve the immobilization of a recognition element such as DNA onto the surface of TMDs. Therefore, it is imperative to...

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Main Authors: Loo, Adeline Huiling, Bonanni, Alessandra, Sofer, Zdenek, Pumera, Martin
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2015
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在線閱讀:https://hdl.handle.net/10356/103752
http://hdl.handle.net/10220/25877
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機構: Nanyang Technological University
語言: English
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總結:Owing to the attractive properties that transition metal dichalcogenides (TMDs) display, they have found recent application in the fabrication of biosensing devices. These devices involve the immobilization of a recognition element such as DNA onto the surface of TMDs. Therefore, it is imperative to examine the interactions between TMDs and DNA. Herein, we explore the effect of different transition metals (Mo and W) and chalcogens (S and Se) on the interactions between hairpin DNA and TMDs of both bulk and t-BuLi exfoliated forms. We discovered that the interactions are strongly dependent on the metal/chalcogen composition in TMDs.