[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

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Main Authors:	Kumaran, Elumalai, Fan, Wai Yip, Leong, Weng Kee
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:	https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-103801
record_format	dspace
spelling	sg-ntu-dr.10356-1038012023-02-28T19:37:58Z [CpIrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds CpIrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies. MOE (Min. of Education, S’pore) Accepted version 2014-12-26T04:34:28Z 2019-12-06T21:20:35Z 2014-12-26T04:34:28Z 2019-12-06T21:20:35Z 2014 2014 Journal Article Kumaran, E., Fan, W. Y., & Leong, W. K. (2014). [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines. Organic letters, 16(5), 1342-1345. https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539 10.1021/ol5000692 en Organic letters © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/ol5000692]. 5 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
description	Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee
format	Article
author	Kumaran, Elumalai Fan, Wai Yip Leong, Weng Kee
author_sort	Kumaran, Elumalai
title	[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
title_short	[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
title_full	[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
title_fullStr	[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
title_full_unstemmed	[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
title_sort	[cp*ircl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines
publishDate	2014
url	https://hdl.handle.net/10356/103801 http://hdl.handle.net/10220/24539
_version_	1759853430021554176

[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

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