The unexpected reactions of boron trihalides with 7-phosphanorbornadiene complexes

The reactions of BX3 (X = Cl, Br) with 7-R-7-phosphanorbornadiene–M(CO)5 (M = Mo, W) complexes (1) yields products 2 and 4 in which the RP–M(CO)5 unit is inserted into one of the carboxyl units of the phthalic derivative as a result of the collapse of the bridge. When X = Br, 4 cyclizes to give new...

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Bibliographic Details
Main Authors: Mei, Yanbo, Tian, Rongqiang, Duan, Zheng, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:https://hdl.handle.net/10356/103961
http://hdl.handle.net/10220/24661
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Institution: Nanyang Technological University
Language: English