The unexpected reactions of boron trihalides with 7-phosphanorbornadiene complexes
The reactions of BX3 (X = Cl, Br) with 7-R-7-phosphanorbornadiene–M(CO)5 (M = Mo, W) complexes (1) yields products 2 and 4 in which the RP–M(CO)5 unit is inserted into one of the carboxyl units of the phthalic derivative as a result of the collapse of the bridge. When X = Br, 4 cyclizes to give new...
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Main Authors: | , , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2015
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/103961 http://hdl.handle.net/10220/24661 |
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Institution: | Nanyang Technological University |
Language: | English |