The unexpected reactions of boron trihalides with 7-phosphanorbornadiene complexes

• المؤلفون الرئيسيون: Mei, Yanbo, Tian, Rongqiang, Duan, Zheng, Mathey, François
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Chemistry::Inorganic chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/103961; http://hdl.handle.net/10220/24661

The reactions of BX3 (X = Cl, Br) with 7-R-7-phosphanorbornadiene–M(CO)5 (M = Mo, W) complexes (1) yields products 2 and 4 in which the RP–M(CO)5 unit is inserted into one of the carboxyl units of the phthalic derivative as a result of the collapse of the bridge. When X = Br, 4 cyclizes to give new...