Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus

Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus

Electrophilic terminal phosphinidene complexes [Ar-Ar-P-W(CO)5] (Ar-Ar: biaryl or an analogue thereof) undergo a spontaneous insertion of the phosphorus atom into the vicinal C-H bonds to give annelated phospholes. Twelve examples are described, including biphenyl, thienyl, pyrrolyl, and benzofuryl...

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Main Authors: Wei, Xinda, Lu, Zongming, Zhao, Xu, Duan, Zheng, Mathey, Francois
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2015
Subjects:
DRNTU::Science::Chemistry
Online Access:https://hdl.handle.net/10356/103967
http://hdl.handle.net/10220/24636
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1039672020-03-07T12:34:54Z Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus Wei, Xinda Lu, Zongming Zhao, Xu Duan, Zheng Mathey, Francois School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Electrophilic terminal phosphinidene complexes [Ar-Ar-P-W(CO)5] (Ar-Ar: biaryl or an analogue thereof) undergo a spontaneous insertion of the phosphorus atom into the vicinal C-H bonds to give annelated phospholes. Twelve examples are described, including biphenyl, thienyl, pyrrolyl, and benzofuryl groups as biaryl moieties. The activation energy of the insertion reaction is quite low (about 2 kcal mol−1). 2015-01-15T08:00:34Z 2019-12-06T21:23:40Z 2015-01-15T08:00:34Z 2019-12-06T21:23:40Z 2015 2015 Journal Article Wei, X., Lu, Z., Zhao, X., Duan, Z., & Mathey, F. (2015). Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus. Angewandte chemie international edition, 54(5), 1583-1586. 1433-7851 https://hdl.handle.net/10356/103967 http://hdl.handle.net/10220/24636 10.1002/anie.201410603 en Angewandte chemie international edition © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry
spellingShingle DRNTU::Science::Chemistry
Wei, Xinda
Lu, Zongming
Zhao, Xu
Duan, Zheng
Mathey, Francois
Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
description Electrophilic terminal phosphinidene complexes [Ar-Ar-P-W(CO)5] (Ar-Ar: biaryl or an analogue thereof) undergo a spontaneous insertion of the phosphorus atom into the vicinal C-H bonds to give annelated phospholes. Twelve examples are described, including biphenyl, thienyl, pyrrolyl, and benzofuryl groups as biaryl moieties. The activation energy of the insertion reaction is quite low (about 2 kcal mol−1).
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wei, Xinda
Lu, Zongming
Zhao, Xu
Duan, Zheng
Mathey, Francois
format Article
author Wei, Xinda
Lu, Zongming
Zhao, Xu
Duan, Zheng
Mathey, Francois
author_sort Wei, Xinda
title Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
title_short Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
title_full Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
title_fullStr Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
title_full_unstemmed Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
title_sort synthesis of annelated phospholes through intramolecular c-h activation by monovalent phosphorus
publishDate 2015
url https://hdl.handle.net/10356/103967
http://hdl.handle.net/10220/24636
_version_ 1681049527990091776

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