A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes

A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes

Three stereogenic centers in a row: The unconventional activation of enal compounds mediated by an N-heterocyclic carbene (NHC) has generated three consecutive reactive carbon centers that undergo highly regio- and stereoselective annulations with di(enone)s to generate benzotricyclic products conta...

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Main Authors: Fang, Xinqiang, Kun, Jiang, Xing, Chong, Hao, Lin, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Organic chemistry
Online Access:https://hdl.handle.net/10356/104148
http://hdl.handle.net/10220/19454
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Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-104148
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spelling sg-ntu-dr.10356-1041482020-03-07T12:34:57Z A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes Fang, Xinqiang Kun, Jiang Xing, Chong Hao, Lin Chi, Robin Yonggui School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry Three stereogenic centers in a row: The unconventional activation of enal compounds mediated by an N-heterocyclic carbene (NHC) has generated three consecutive reactive carbon centers that undergo highly regio- and stereoselective annulations with di(enone)s to generate benzotricyclic products containing multiple stereogenic centers (see scheme). 2014-05-26T03:07:11Z 2019-12-06T21:27:32Z 2014-05-26T03:07:11Z 2019-12-06T21:27:32Z 2011 2011 Journal Article Fang, X., Kun, J., Xing, C., Hao, L., & Chi, Y. R. (2011). A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes. Angewandte Chemie International Edition, 50(8), 1910–1913. https://hdl.handle.net/10356/104148 http://hdl.handle.net/10220/19454 10.1002/anie.201007144 158201 en Angewandte Chemie international edition © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Organic chemistry
spellingShingle DRNTU::Science::Chemistry::Organic chemistry
Fang, Xinqiang
Kun, Jiang
Xing, Chong
Hao, Lin
Chi, Robin Yonggui
A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
description Three stereogenic centers in a row: The unconventional activation of enal compounds mediated by an N-heterocyclic carbene (NHC) has generated three consecutive reactive carbon centers that undergo highly regio- and stereoselective annulations with di(enone)s to generate benzotricyclic products containing multiple stereogenic centers (see scheme).
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Fang, Xinqiang
Kun, Jiang
Xing, Chong
Hao, Lin
Chi, Robin Yonggui
format Article
author Fang, Xinqiang
Kun, Jiang
Xing, Chong
Hao, Lin
Chi, Robin Yonggui
author_sort Fang, Xinqiang
title A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
title_short A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
title_full A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
title_fullStr A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
title_full_unstemmed A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
title_sort highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by n-heterocyclic carbenes
publishDate 2014
url https://hdl.handle.net/10356/104148
http://hdl.handle.net/10220/19454
_version_ 1681043468453937152

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