VO2/Si–Al gel nanocomposite thermochromic smart foils : largely enhanced luminous transmittance and solar modulation

VO2 nanoparticles with a dimension of approximately 20nm were obtained by simple mechanical bead-milling method, which were well dispersed in transparent silica-alumina (Si-Al) gel matrix to form nanocomposites. The VO2/Si-Al gel thermochromic nanocomposite foils were fabricated with various VO2 sol...

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Bibliographic Details
Main Authors: Liu, C., Cao, X., Kamyshny, A., Magdassi, S., Long, Y., Law, J. Y.
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/104166
http://hdl.handle.net/10220/19424
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Institution: Nanyang Technological University
Language: English
Description
Summary:VO2 nanoparticles with a dimension of approximately 20nm were obtained by simple mechanical bead-milling method, which were well dispersed in transparent silica-alumina (Si-Al) gel matrix to form nanocomposites. The VO2/Si-Al gel thermochromic nanocomposite foils were fabricated with various VO2 solid contents and foil thickness. With 10% VO2 loading and 3μm foil thickness, high luminous transmittance (Tlum(20°C)=63.7% and Tlum(90°C)=54.4%), and large solar modulation ability (ΔTsol=12%) can be obtained which surpasses the best reported results (nanoporous films:Tlum(20°C)=43.3%, Tlum(90°C)=39.9% and ΔTsol=14.1%). This current approach provided a simple and scalable preparation method with the best combined thermochromic performance.