Synthesis of heterocycles through transition metal-catalyzed isomerization reactions
Metal-catalyzed isomerization of N- and O-allylic systems is emerging as an effective method to form synthetically useful iminium and oxocarbenium intermediates. In the presence of tethered nucleophiles, several recent examples illuminate this approach as a powerful strategy for the synthesis of str...
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sg-ntu-dr.10356-1051452019-12-06T21:46:30Z Synthesis of heterocycles through transition metal-catalyzed isomerization reactions Ishoey, Mette Nielsen, Thomas E. DRNTU::Science::Chemistry Metal-catalyzed isomerization of N- and O-allylic systems is emerging as an effective method to form synthetically useful iminium and oxocarbenium intermediates. In the presence of tethered nucleophiles, several recent examples illuminate this approach as a powerful strategy for the synthesis of structurally complex and diverse heterocycles. In this Concept article, we attempt to cover this area of research through a selection of recent versatile examples. 2014-09-08T08:23:38Z 2019-12-06T21:46:30Z 2014-09-08T08:23:38Z 2019-12-06T21:46:30Z 2014 2014 Journal Article Ishoey, M., & Nielsen, T. E. (2014). Synthesis of heterocycles through transition metal-catalyzed isomerization reactions. Chemistry - A European journal, 20(29), 8832-8840. 0947-6539 https://hdl.handle.net/10356/105145 http://hdl.handle.net/10220/20463 http://dx.doi.org/10.1002/chem.201400216 en Chemistry - A European journal © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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DRNTU::Science::Chemistry Ishoey, Mette Nielsen, Thomas E. Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| description |
Metal-catalyzed isomerization of N- and O-allylic systems is emerging as an effective method to form synthetically useful iminium and oxocarbenium intermediates. In the presence of tethered nucleophiles, several recent examples illuminate this approach as a powerful strategy for the synthesis of structurally complex and diverse heterocycles. In this Concept article, we attempt to cover this area of research through a selection of recent versatile examples. |
| format |
Article |
| author |
Ishoey, Mette Nielsen, Thomas E. |
| author_facet |
Ishoey, Mette Nielsen, Thomas E. |
| author_sort |
Ishoey, Mette |
| title |
Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| title_short |
Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| title_full |
Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| title_fullStr |
Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| title_full_unstemmed |
Synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| title_sort |
synthesis of heterocycles through transition metal-catalyzed isomerization reactions |
| publishDate |
2014 |
| url |
https://hdl.handle.net/10356/105145 http://hdl.handle.net/10220/20463 http://dx.doi.org/10.1002/chem.201400216 |
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1681040123750252544 |