Casimir-Polder effect with thermally excited surfaces

• Main Authors: Laliotis, A., Ducloy, Martial Auguste Adonis
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Physical chemistry::Quantum chemistry
• Online Access: https://hdl.handle.net/10356/105265; http://hdl.handle.net/10220/25989
• Institution: Nanyang Technological University

We take a closer look at the fundamental Casimir-Polder (CP) interaction between quantum particles and dispersive dielectric surfaces with surface polariton or plasmon resonances. Linear response theory shows that in the near-field, van der Waals regime the free-energy shift of a particle contains a thermal component that depends exclusively on the excitation of the evanescent surface polariton (plasmon or phonon) modes. Our work makes evident the link between particle surface interaction and near-field thermal emission and demonstrates how this can be used to engineer Casimir-Polder forces. We also examine how the exotic effects of surface waves are washed out as the distance from the surface increases. In the case of molecules or excited-state atoms, far-field approximations result in a classical dipole-dipole interaction which depends on the surface reflectivity and the mean number of photons at the frequency of the atomic or molecular transition. Finally we present numerical results for the CP interaction between Cs atoms and various dielectric surfaces with a single polariton resonance and discuss the implications of temperature and retardation effects for specific spectroscopic experiments.