Iridium(III)-catalyzed selective and mild C-H amidation of cyclic N-sulfonyl ketimines with organic azides

• المؤلفون الرئيسيون: Maraswami, Manikantha, Chen, Gang, Loh, Teck-Peng
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2019
• الموضوعات: Amidation; Sultams; DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/105612; http://hdl.handle.net/10220/48716
• المؤسسة: Nanyang Technological University

A general protocol for iridium catalyzed direct C−H amidation of cyclic N‐sulfonyl ketimines using sulfonyl, acyl and aryl azides as nitrogen source is reported herein. The reaction takes place at room temperature with acyl and aryl azides, while an elevated temperature needed with sulfonyl azides t...