Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism
The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P–N bond cle...
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sg-ntu-dr.10356-1062172023-02-28T19:29:16Z Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism Gurnani, Chitra Đorđević, Nemanja Muthaiah, Senthilkumar Dimić, Dušan Ganguly, Rakesh Petković, Milena Vidović, Dragoslav School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Carbanions The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P–N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. Accepted version 2015-07-07T09:19:58Z 2019-12-06T22:06:39Z 2015-07-07T09:19:58Z 2019-12-06T22:06:39Z 2015 2015 Journal Article Gurnani, C., Đorđević, N., Muthaiah, S., Dimić, D., Ganguly, R., Petković, M., et al. (2015). Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism. Chemical communications, 51(53), 10762-10764. https://hdl.handle.net/10356/106217 http://hdl.handle.net/10220/26342 10.1039/C5CC03194J en Chemical communications © 2015 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Communications, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C5CC03194J]. application/pdf |
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DRNTU::Science::Chemistry::Organic chemistry::Carbanions Gurnani, Chitra Đorđević, Nemanja Muthaiah, Senthilkumar Dimić, Dušan Ganguly, Rakesh Petković, Milena Vidović, Dragoslav Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| description |
The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P–N bond cleavage that, according to computational studies, occurred via an SN2′-like mechanism. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Gurnani, Chitra Đorđević, Nemanja Muthaiah, Senthilkumar Dimić, Dušan Ganguly, Rakesh Petković, Milena Vidović, Dragoslav |
| format |
Article |
| author |
Gurnani, Chitra Đorđević, Nemanja Muthaiah, Senthilkumar Dimić, Dušan Ganguly, Rakesh Petković, Milena Vidović, Dragoslav |
| author_sort |
Gurnani, Chitra |
| title |
Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| title_short |
Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| title_full |
Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| title_fullStr |
Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| title_full_unstemmed |
Extending the chemistry of carbones : P-N bond cleavage via an SN2′-like mechanism |
| title_sort |
extending the chemistry of carbones : p-n bond cleavage via an sn2′-like mechanism |
| publishDate |
2015 |
| url |
https://hdl.handle.net/10356/106217 http://hdl.handle.net/10220/26342 |
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1759857035555373056 |